Kinetics and oxidation of thiocarbohydrazide by hexacyanoferrate(III) in aqueous perchloric acid medium

Ravindra Kannappa Seetharam; Vidyavati Ashok Shastry; Siddalingiah Shashidhar; Mohan Kumar

doi:10.59400/n-c.v1i1.265

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Kinetics and oxidation of thiocarbohydrazide by hexacyanoferrate(III) in aqueous perchloric acid medium

Ravindra Kannappa Seetharam, Vidyavati Ashok Shastry, Siddalingiah Shashidhar, Mohan Kumar

Abstract

Hexacyanoferrate(III) [HCF(III)] was used to oxidize thiocarbohydrazide (TCH) in an aqueous perchloric acid (HClO₄) medium, and the reaction kinetics were studied spectrophotometrically at 420 nm while keeping a constant ionic strength of 1.0 mol dm⁻³ and modulating the temperature between 298K–318K. The stoichiometry of the reaction among TCH and HCF in the HClO₄ medium is 1:2. The reaction has a lower than unit order in both TCH and HClO₄ and is of the first order in HCF. The impact of varying the ionic strength and dielectric constant of the medium on the rate has been investigated. The effect of temperature on the reaction rate was studied, and different activation parameters of reaction Ea, ΔH^#, ΔS^#, ΔG^#, and log₁₀ A were calculated. The products of oxidation were analyzed by simple qualitative analysis. On the basis of the collected data, the rate law has been derived, and a probable mechanism has been proposed.

Keywords

thiocarbohydrazide; hexacyanoferrate; oxidation; kinetics; mechanism

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DOI: https://doi.org/10.59400/n-c.v1i1.265
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